| silver, Ag, 47 |
|
transition metals |
|
11,
5,
d |
lustrous white metal
 |
|
107.8682(2)
g·mol−1 |
| [Kr]
4d10 5s1 |
| 2, 8, 18, 18, 1 |
|
silver |
|
solid |
| 10.49 g·cm−3 |
| 9.320 g·cm−3 |
1234.93 K
(961.78 °C,
1763.2 °F) |
2435 K
(2162 °C,
3924 °F) |
| 11.28 kJ·mol−1 |
| 258 kJ·mol−1 |
| (25 °C) 25.350 J·mol−1·K−1 |
| face-centered cubic |
1
(amphoteric
oxide) |
| 1.93 (Pauling scale) |
| 1st: 731.0
kJ/mol |
| 2nd: 2070 kJ/mol |
| 3rd: 3361 kJ/mol |
|
160 pm |
|
165 pm |
|
153 pm |
|
172 pm |
|
diamagnetic |
| (20 °C) 15.87 n Ω·m |
| (300 K) 429 W·m−1·K−1 |
| (300 K) 174
mm˛/s |
| (25 °C) 18.9 µm·m−1·K−1 |
| (r.t.)
2680 m·s−1 |
| 83 GPa |
| 30 GPa |
| 100 GPa |
| 0.37 |
| 2.5 |
| 251 MPa |
| 24.5 MPa |
| 7440-22-4 |
Silver (IPA:
/ˈsɪlvə(ɹ)/)
is a
chemical element with the symbol Ag (Latin:
argentum). A soft
white lustrous
transition metal, it has the highest electrical and thermal
conductivity of for a metal, and occurs in
minerals and in free form. This metal is used in
coins,
jewelry,
tableware,
photography, and in
mirrors.
Notable characteristics
Silver is a very ductile and malleable (slightly harder than
gold)
univalent
coinage metal with a brilliant white metallic luster that
can take a high degree of
polish. It has the highest
electrical conductivity of all
metals, even higher than copper, but its greater cost and
tarnishability has prevented it from being widely used in place
of copper for electrical purposes, though it was used in the
electromagnets used for enriching
Uranium during
World War II (mainly because of the wartime shortage of
copper).
Pure silver has the highest
thermal conductivity, whitest color, the highest optical
reflectivity (although
aluminium slightly outdoes it in parts of the visible
spectrum, and is a poor reflector of
ultraviolet light), and the lowest contact resistance of any
metal. Silver halides are photosensitive and are remarkable for
the effect of light upon them. This metal is stable in pure air
and water, but does tarnish when it is exposed to
ozone,
hydrogen sulfide, or air containing sulfur. The most common
oxidation state of silver is +1 (for example, silver
nitrate, AgNO3); a few +2 (for example,
silver(II) fluoride; AgF2) and +3 compounds (for
example,
silver(III) persulfate; Ag2(SO5)3)
are also known.
Applications of antique silver
A major use of silver is as a
precious metal.
Sterling silver is 92.5 % silver, alloyed usually with
copper. Jewelry and silverware are traditionally made from this.
Silver is used in medals, denoting second place. Many high end
musical instruments are made with silver, which benefit from
a higher tone quality.[citation
needed]
The name of United Kingdom monetary unit 'Pound' originally
had the value of one troy pound of sterling silver. Silver has
been coined to produce money since
700
BC by the
Lydians, in the form of
electrum. Later, silver was refined and coined in its pure
form. The words for "silver" and "money" are the same in at
least 14 languages.
The largest single end use[citation
needed] of silver is photography, in the
form of
silver nitrate and silver
halides are widely used in photography — 30 % of US
production is used here.[1]
Some electrical and electronic products use silver for its
superior conductivity, even when tarnished. For example, printed
circuits are made using silver paints,[1]
and computer keyboards use silver electrical contacts. silver
cadmium oxide is used in high voltage contacts because it can
minimize
arcing. Silver is also used to make
solder and brazing alloys,
electrical contacts, and high capacity silver-zinc
and silver-cadmium
batteries. Silver in a thin layer of on top of a bearing
material can provide a significant increase in galling
resistance and reduce wear under heavy load, particularly
against steel.
Mirrors which need superior reflectivity for visible light
are made with silver as the reflecting material in a process
called
silvering, though common mirrors are backed with aluminium.
Using a process called
sputtering, silver (and sometimes gold) can be applied to
glass at various thicknesses, allowing different amounts of
light to penetrate. This is most often seen in architectural
glass and tinted windows on vehicles.
Silver's catalytic properties make it ideal for use as a
catalyst in oxidation reactions; for example, the production
of
formaldehyde from
methanol and air by means of silver screens or
crystallites containing a minimum 99.95 weight-percent
silver. Silver (upon some suitable support) is probably the only
catalyst available today to convert
ethylene to
ethylene oxide (later hydrolyzed to
ethylene glycol, used for making
polyesters)—a very important industrial reaction.
Oxygen dissolves in silver relatively easily compared to
other gases present in air. Attempts have been made to construct
silver
membranes of only a few
monolayers thickness. Such a membrane could be used to
filter pure oxygen from air.
Antique Silver
In medicine
Hippocrates, the father of modern medicine, wrote that
silver had beneficial healing and anti-disease properties, and
the Phoenicians used to store water, wine, and vinegar in silver
bottles to prevent spoiling. In the early 1900s people would put
silver dollars in milk bottles to prolong the milk's
freshness. Silver compounds were used successfully to prevent
infection in
World War I before the advent of
antibiotics. Silver nitrate solution was a standard of care
but was largely replaced by
silver sulfadiazine cream (SSD Cream) which was generally
the "standard of care" for the antibacterial/antibiotic
treatment of serious burns until the late 1990's. Now, other
options such as silver coated dressings (activated silver
dressings) are used in addition to SSD cream, and may present
advantages such as pain reduction and capacity for treatment at
home.
The widespread use of silver went out of fashion with the
development of modern antibiotics. However, recently there has
been renewed interest in silver as a broad spectrum
antimicrobial. In particular, it is being used with alginate, a
naturally occurring
biopolymer derived from seaweed, in a range of
silver alginate products designed to prevent infections as
part of
wound
management procedures, particularly applicable to
burn victims. In addition,
Samsung has introduced washing machines with a final rinse
containing silver ions to provide several days of antibacterial
protection in the clothes.[2]
Additionally, Kohler has introduced a line of toilets that have
silver ions embedded in the porcelain to kill germs.
The malleability, non-toxicity and beauty of silver make it
useful in
dental alloys for fittings and fillings.
Health precautions
Silver plays no known natural biological role in humans, and
possible health effects of silver are a subject of dispute.
Silver itself is not toxic but most
silver salts are, and some may be
carcinogenic.
Silver and compounds containing silver (like
colloidal silver) can be absorbed into the
circulatory system and become deposited in various body
tissues leading to a condition called
argyria which results in a blue-grayish pigmentation of the
skin, eyes, and
mucous membranes. Although this condition does not harm a
person's health, it is disfiguring and usually permanent.
Argyria is rare and mild forms are sometimes mistaken for
cyanosis.
Silver-ions and silver compounds show a toxic effect on some
bacteria, viruses, algae and fungi typical for heavy metals like
lead or
mercury, but without the high toxicity to humans that is
normally associated with them. Its germicidal effects kill many
microbial organisms
in vitro (i.e. in a
test tube or a
petri dish). The exact process by which this is done is
still not well understood, although different theories exist.
One of these is a process generally known for heavy metals
called the
oligodynamic effect, which goes a long way explaining the
effect on microbial lifeforms but does not explain certain
antiviral functions.
Alternative medicine
Today, various kinds of silver compounds, or devices to make
solutions or
colloids containing silver, are sold as remedies for a wide
variety of diseases. Although mostly harmless, some people using
these home-made solutions use far too much and develop argyria
over a period of months or years, and several have been
documented in the last few years in the medical literature,
including one possible case of coma associated with a high
intake of silver (see medical references). It is strongly
advised to notify a doctor when taking silver as a form of
self-medication.
Other silver compounds
Antique Silver History
Alchemical symbol for silver
Silver (from
Turkic çılbır (chain); through
Anglo-Saxon seolfor; compare
Old High German silabar; Ag is from the Latin
argentum) has been known since ancient times. It is
mentioned in the
book of Genesis, and slag heaps found in
Asia Minor and on the islands of the
Aegean Sea indicate that silver was being separated from
lead
as early as the
4th millennium BC.
Silver has been used for thousands of years for
ornaments and
utensils, for
trade,
and as the basis for
monetary systems. Its value as a
precious metal was long considered second only to gold. In
Ancient Egypt and
Medieval Europe, it was often more valuable than gold.
Judas Iscariot is infamous for having, according to the
New Testament, taken a bribe of thirty pieces of silver from
religious leaders in
Jerusalem to turn
Jesus Christ over to the Romans.
Associated with the
moon,
as well as with the sea and various lunar
goddesses, the metal was referred to by alchemists by the
name luna. One of the
alchemical symbols for silver is a crescent moon with the
open part on the left (see picture, left).
The metal
mercury was thought of as a kind of silver, though the two
elements are chemically unrelated; its Latin and
English names, hydrargyrum ("watery silver") and
quicksilver, respectively, reflect this history.
In
heraldry, the
argent, in addition to being shown as silver (this has been
shown at times with real silver in official representations),
can also be shown as white. Occasionally, the word "silver" is
used rather than argent; sometimes this is done
across-the-board, sometimes to avoid repetition of the word
"argent" in blazon.
Europeans found a huge amount of silver in the
New World in
Zacatecas and
Potosí, which triggered a period of inflation in Europe. The
conquistador
Pizarro was said to have resorted to having his horses shod
with silver horseshoes due to the metal's abundance, in contrast
to the relative lack of iron in
Peru.
Silver, which was extremely valuable in
China,
became a global commodity, contributing to the rise of the
Spanish Empire. The rise and fall of its value affected the
world market.
The
Rio de la Plata was named after silver (in
Spanish, plata), and in turn lent the meaning of its
name to
Argentina.
Silver mining was a driving force in the settlement of
western North America, with major booms for silver and
associated minerals (primarily lead) in the galena ore silver is
most commonly found in. Notable
"silver rushes" were in
Colorado,
Nevada,
Cobalt, Ontario ,
California and the
Kootenay region of British Columbia, notably in the
Boundary and
"Silvery Slocan". The largest silver ore deposits in the
United States were discovered at the
Comstock Lode in Virginia City, Nevada, in 1859. In northern
Idaho the world-famous Sunshine Mine, the richest silver mine in
American history, has had more than 350 million ounces of
production over the past century.At the time of its closure in
early 2001, the Sunshine was producing at a rate of over three
million ounces of silver per year at an average grade of
approximately twenty ounces per ton. The prior operator last
estimated the mine reserves at 26.75 million ounces of silver,
10.36 million pounds of copper and 7.05 million pounds of lead
(or approximately 28.85 million ounces of silver-equivalent), as
well as an additional resource of 159.66 million ounces of
silver.
Occurrence and extraction
Silver ore (Lincoln cent is shown for scale)
-
Silver is found in native form, combined with
sulfur,
arsenic,
antimony, or
chlorine and in various ores such as
argentite (Ag2S) and
horn silver (AgCl). The principal sources of silver are
copper, copper-nickel, gold, lead and lead-zinc ores obtained
from
Canada,
Mexico (historically
Batopilas),
Peru,
Australia and the
United States.
This metal can also produced during the
electrolytic refining of copper and by application of the
Parkes process on lead metal obtained from lead ores that
contain small amounts of silver. Commercial grade fine silver is
at least 99.9% pure silver and purities greater than 99.999% are
available.
Mexico is the world's largest silver producer. According to
the Secretary of Economics of Mexico, it produced 80,120,000
troy
ounces (2492
metric tons) in 2000, about 15% of the annual production of
the world.
Price
-
Silver is currently about 1/50th the price of gold by mass,
and approximately 70 times more valuable than
copper. Silver did once trade at 1/6th to 1/12th the price
of gold, prior to the
Age of Discovery and the discovery of great silver deposits
in the Americas, most notably the vast
Comstock Lode in
Virginia City,
Nevada, USA. This then resulted in the debate over cheap
Free Silver to benefit the agricultural sector was among the
most prolongued and difficult in that country's history and
dominated public discourse during the latter decades of the
nineteenth century.
Over the last 100 years the price of silver and the
gold/silver price ratio has fluctuated greatly due to competing
industrial and
store of value demands. In 1980 the silver price rose to an
all-time high of US$49.45 per
troy ounce. By December 2001 the price had fallen to US$4.15
per ounce, and in May 2006 it had risen back as high as US$15.21
per ounce.
As of 2006, current silver prices (and most other metal
prices) have been rather volatile, for example quickly dropping
from the May high of US$15.21 per ounce to a June low of US$9.60
per ounce before rising back above US$12 per ounce by August.[3]
Isotopes
Naturally occurring silver is composed of the two stable
isotopes 107Ag and 109Ag with 107Ag
being the more abundant (51.839%
natural abundance). Twenty-eight
radioisotopes have been characterised with the most stable
being 105Ag with a
half-life of 41.29 days, 111Ag with a half-life
of 7.45 days, and 112Ag with a half-life of 3.13
hours.
All of the remaining
radioactive isotopes have half-lifes that are less than an
hour and the majority of these have half lifes that are less
than 3 minutes. This element has numerous
meta states with the most stable being 108mAg (t*
418 years), 110mAg (t* 249.79 days)
and 106mAg (t* 8.28 days).
Isotopes of silver range in
atomic weight from 93.943
u (94Ag) to 123.929 u (124Ag). The
primary
decay mode before the most abundant stable isotope, 107Ag,
is
electron capture and the primary mode after is
beta decay. The primary
decay products before 107Ag are
palladium (element 46) isotopes and the primary products
after are
cadmium (element 48) isotopes.
The palladium
isotope 107Pd decays by beta emission to 107Ag
with a half-life of 6.5 million years.
Iron
meteorites are the only objects with a high enough
palladium/silver ratio to yield measurable variations in
107Ag abundance.
Radiogenic 107Ag was first discovered in the
Santa Clara meteorite in
1978.
The discoverers suggest that the coalescence and
differentiation of iron-cored small
planets may have occurred 10 million years after a
nucleosynthetic event. 107Pd versus Ag
correlations observed in bodies, which have clearly been melted
since the
accretion of the
solar system, must reflect the presence of live short-lived
nuclides in the early solar system.
Antique Silver
Folklore and Mass Culture
Because of the mysticism surrounding silver's
lunar
associations, as well as the aesthetic qualities of the white,
reflective metal that cause it to be associated with purity,
silver in European
Folklore has long been traditionally believed to be an
antidote to various maladies and fictional
monsters. Notably, silver was believed to be a repellant
against
vampires (this primarily originates from its holy
connotations; also, mirrors were originally polished silver, and
as such, vampires allegedly cannot be seen in them because they
are wicked) and it was believed that a
werewolf, in his bestial form, could only be killed by a
weapon or bullet made of silver, and was equally effective
against vampires, as described in Eastern European folklore.
This has given rise to the term "silver
bullet," which is used to describe things that very
effectively deal with one specific problem.
The
Lone Ranger of radio serials, comic strips, and some TV
programs leaves a silver bullet as a calling card.